creators_name: 0717011049, MUHAMMAD ISHOM
type: article
datestamp: 2015-11-20 02:04:00
lastmod: 2015-11-20 02:04:00
metadata_visibility: show
title: PROSES PENCETAKAN ION DALAM SINTESIS HIBRIDA ORGANOSILIKA UNTUK ADSORPSI SELEKTIF ION Pb(II)
DARI LARUTAN
ispublished: pub
subjects: General
full_text_status: restricted
abstract: Abstrak

Sintesis material hibrida amino silika (HAS) dan hibrida merkapto silika (HMS)
tercetak ion Pb(II) (HAS-t-Pb(II) dan HMS-t-Pb(II)) telah dilakukan
menggunakan senyawa aktif 3-aminopropiltrimetoksisilan (3-APTMS) dan 3-
merkaptopropiltrimetoksisilan (3-MPTMS) dengan prekursor tetraetilortosilikat
(TEOS). Karakterisasi material hasil sintesis tersebut menggunakan
spektrofotometer inframerah (IR) dan Scanning Electron Microscope- Energy
Dispersive X-Ray Spectrometer (SEM-EDX). Kadar ion logam dianalisis
menggunakan spektrofotometer serapan atom (SSA). Perbandingan kemampuan
adsorpsi material HAS dengan HAS-t-Pb(II) dan HMS dengan HMS-t-Pb(II)
dilakukan melalui uji adsorpsi yang meliputi laju, kapasitas dan selektivitas
adsorpsi terhadap ion logam Pb(II). Laju adsorpsi ditentukan menggunakan
kinetika pseudo orde dua dengan nilai konstanta laju (k2) untuk HAS-t-Pb(II) dan
HMS-t-Pb(II) masing-masing 1,07 dan 33,30 g mmol-1 menit-1. Kapasitas
adsorpsi material HAS-t-Pb(II) dan HMS-t-Pb(II) mengikuti persamaan isoterm
Langmuir dengan nilai masing-masing 15,15 dan 29,41 mol g-1. Material HAS-tPb(II) dan HMS-t-Pb(II) lebih selektif terhadap ion Pb(II) dibandingkan Zn(II),
Ni(II) dan Cd(II) dengan koefisien selektivitas (α) > 1. Selektivitas material HASt-Pb(II) dan HMS-t-Pb(II) masing-masing meningkat hingga 2,41 dan 3,58 kali
lebih selektif terhadap ion Pb(II) dibandingkan material HAS dan HMS.
Kata Kunci : Hibrida Amino Silika, Hibrida Merkapto Silika, Adsorpsi selektif










Abstract

The synthesis of material amino silica hybrid (HAS) and merkapto silica hybrid
(HMS) imprinted ions Pb(II) (HAS-t-Pb(II)) and (HMS-t-Pb(II)) has been conducted
using a compound of active 3-aminopropiltrimetoksisilan (3-APTMS) and 3-
merkaptopropiltrimetoksisilan (3-MPTMS) with the precursor of the
tetraetilortosilikat (TEOS). Characterization result of materials synthesis using
spectrophotometer infrared (IR) and Scanning Electron Microscope- Energy
Dispersive X-Ray Spectrometer (SEM-EDX). The levels of metal ions are analyzed
using atomic absorption spectrophotometer (AAS). Comparison of ability of
adsorption material HAS with HAS-t-Pb(II) and HMS with HMS-t-Pb(II) done via a
test that includes a rate, adsorption capacity and selectivity adsorption of metal ions,
Pb(II). The rate of adsorption is determined using the pseudo first order kinetics with
two rate constants (k2) to HAS-t-Pb(II) and HMS-t-Pb(II) each 1,07 and 33,30 g
mmol-1 min-1. Adsorption capacity of the material HAS-t-Pb (II) and HMS-t-Pb(II)
follow the Langmuir equation isoterm with each value 15,15 and 29,41 mol g-1. The
Material HAS-t-Pb(II) and HMS-t-Pb(II) more selective of Pb(II) ions than Zn(II),
Ni(II) and Cd(II) with selectivity coefficient (α)> 1. Selectivity material HAS-tPb(II) and HMS-t-Pb (II) each rising to 2,41 and 3,58 times more selective for the
Pb(II) ions compared HAS and HMS material.
Keyword : Amino Slica Hybrid, Mercapto Silica Hybrid, Selective Adsorption.
date: 2012-02-03
date_type: published
publication: Digital Library
refereed: TRUE
citation:   0717011049, MUHAMMAD ISHOM  (2012) PROSES PENCETAKAN ION DALAM SINTESIS HIBRIDA ORGANOSILIKA UNTUK ADSORPSI SELEKTIF ION Pb(II) DARI LARUTAN.  Digital Library.       
document_url: http://digilib.unila.ac.id/14529/1/1.%20COVER.pdf
document_url: http://digilib.unila.ac.id/14529/2/2.%20ABSTRAK%20bahasa%20inggris.pdf
document_url: http://digilib.unila.ac.id/14529/3/3.%20ABSTRAK%20bahasa%20indonesia.pdf
document_url: http://digilib.unila.ac.id/14529/4/4.%20COVER%20DALAM.pdf
document_url: http://digilib.unila.ac.id/14529/5/5.%20LEMBAR%20PENGESAHAN.pdf
document_url: http://digilib.unila.ac.id/14529/6/6.%20LEMBAR%20MENGESAHKAN.pdf
document_url: http://digilib.unila.ac.id/14529/7/7.%20RIWAYAT%20HIDUP.pdf
document_url: http://digilib.unila.ac.id/14529/8/8.%20MOTTO.pdf
document_url: http://digilib.unila.ac.id/14529/9/9.%20PERSEMBAHAN.pdf
document_url: http://digilib.unila.ac.id/14529/10/10.%20SANWACANA.pdf
document_url: http://digilib.unila.ac.id/14529/11/14.%20PENDAHULUAN.pdf
document_url: http://digilib.unila.ac.id/14529/12/15.%20TINJAUAN%20PUSTAKA.pdf
document_url: http://digilib.unila.ac.id/14529/13/16.%20METODELOGI%20PENELITIAN.pdf
document_url: http://digilib.unila.ac.id/14529/14/17.%20HASIL%20DAN%20PEMBAHASAN.pdf
document_url: http://digilib.unila.ac.id/14529/15/18.%20KESIMPULAN%20DAN%20SARAN.pdf