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<http://digilib.unila.ac.id/id/eprint/29795> <http://purl.org/dc/terms/title> "ADSORPSI SENYAWA POLISIKLIK AROMATIK HIDROKARBON\r\nFENANTRENA DENGAN MENGGUNAKAN ADSORBEN KARBON\r\nAKTIF DARI SEKAM PADI (Oryza Sativa)"^^<http://www.w3.org/2001/XMLSchema#string> .
<http://digilib.unila.ac.id/id/eprint/29795> <http://purl.org/ontology/bibo/abstract> "Kontaminasi pada air dapat disebabkan oleh suatu senyawa polisiklik aromatik\r\nhidrokarbon (PAH) salah satunya fenantrena. Dalam penelitian ini telah\r\ndilakukan uji adsorpsi dengan menggunakan adsorben karbon aktif dari sekam\r\npadi yang sudah diaktivasi menggunakan ZnCl2 10%. Karakterisasi karbon aktif\r\ndilakukan dengan menggunakan SEM-EDX untuk mengetahui morfologi dan\r\nkomposisi serta digunakan spektrofotometer FT-IR untuk mengidentifikasi gugus\r\nfungsi. Senyawa fenantrena yang teradsorpsi oleh karbon aktif dianalisis dengan\r\nmenggunakan spektrofotometer UV-VIS pada panjang gelombang 250 nm. Uji\r\nadsorpsi dilakukan dengan metode batch untuk menentukan kadar optimum\r\nadsorben, waktu kontak dan konsentrasi adsorbat. Diperoleh hasil optimasi\r\nadsorpsi pada penambahan kadar adsorben 23 mg dengan waktu optimum 60\r\nmenit sebesar 99,93 %. Sedangkan untuk proses adsorpsi pada pengaruh\r\nkonsentrasi fenantrena mengalami penurunan yang dipengaruhi oleh kapasitas\r\nadsorben karbon aktif. Data kinetika adsorpsi fenantrena cenderung mengikuti\r\nmodel kinetika pseudo orde dua dengan nilai koefisien korelasi R2 sebesar 0,921\r\nsedangkan data isoterm adsorpsi fenantrena mengikuti model isoterm Freundlich\r\ndengan nilai koefisien korelasi sebesar 0,991.\r\nKata kunci : Adsorpsi, PAH, Fenantrena, Sekam Padi, Karbon Aktif\r\n\r\nabstract\r\n\r\nThe contamination on water can be caused by hydrocarbon aromatic polycyclic\r\n(HAP) compound, one of them is phenanthrene. In this research,adsorption test\r\nhad been done by using activated carbon adsorbent from rice husk which had been\r\nactivated by using 10% ZnCl2. The characterization of activated carbon was done\r\nby using SEM-EDX to determine the morphology and the composition of sample\r\nand FT-IR was used to identify the functional group. Phenanthrene adsorbed by\r\nactivated carbon analyzed by using Spechtrofotometer UV-VIS on 250 nm\r\nwavelength. Adsorption test was done by using Batch’s method to determine\r\noptimum adsorbent’s mass, optimum contact time, and adsorbate’s concentration.\r\nIt was achieved the adsorption optimation result in addition adsorbent’s mass was\r\n23 mg, optimum time 60 minutes was 99,93%. Moreover for adsorption test on\r\nphenanthrene concentration effect decreased which was caused by activated\r\ncarbon adsorbent capacity. The data of Adsorption kinetics on phenanthrene tend\r\nto follow second pseudo order with the value of coefficient correlation (R2) 0,921\r\nand phenanthrene adsorption isotherm tend to follow Freundlich isotherm model\r\nwith the value of coefficient correlation 0,991.\r\nKeyword : Adsorption, HAP, Phenantrene, Rice Husk, Activated Carbon"^^<http://www.w3.org/2001/XMLSchema#string> .
<http://digilib.unila.ac.id/id/eprint/29795> <http://purl.org/dc/terms/date> "2017-12-22" .
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