?url_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rft.title=SINTESIS%2C+KARAKTERISASI%2C+DAN+APLIKASI+KOMPLEKS%0D%0AKOBALT(II)+DENGAN+LIGAN+1%2C10-+FENANTROLIN+SEBAGAI+DYE%0D%0ASENSITIZER+PADA+DYE+SENSITIZED+SOLAR+CELL+(DSSC)&rft.creator=AURA+DHAYANG+FIARIZKY%2C+1717011064&rft.subject=540+Kimia+dan+ilmu+yang+berhubungan&rft.description=ABSTRAK%0D%0A%0D%0ASINTESIS%2C+KARAKTERISASI%2C+DAN+APLIKASI+KOMPLEKS%0D%0AKOBALT(II)+DENGAN+LIGAN+1%2C10-+FENANTROLIN+SEBAGAI+DYE%0D%0ASENSITIZER+PADA+DYE+SENSITIZED+SOLAR+CELL+(DSSC)%0D%0A%0D%0AOleh%0D%0A%0D%0AAURA+DHAYANG+FIARIZKY%0D%0A%0D%0ATelah+dilakukan+sintesis+senyawa+kompleks+dengan+ion+logam+Co(II)+dan+ligan%0D%0A1%2C10-+Fenantrolin+dengan+perbandingan+konsentrasi+1%3A3.+Senyawa+kompleks+Co(II)%0D%0AFenantrolin+hasil+sintesis+dikarakterisasi+menggunakan+MSB+untuk+mengetahui%0D%0Anilai+momen+magnet%2C+spektrofotometer+UV-Vis+untuk+mengetahui+pergeseran%0D%0Apanjang+gelombang%2C+spektrofotometer+FTIR+untuk+mengetahui+gugus+fungsi+khas%2C%0D%0Aanalisis+DTA-TGA+untuk+mengetahui+formula+dan+dekomposisi+senyawa%2C+dan%0D%0Aanalisis+SEM+untuk+mengetahui+bentuk+morfologi+kristal+senyawa+kompleks.%0D%0ASenyawa+kompleks+Co(II)+Fenantrolin+hasil+sintesis+diaplikasikan+sebagai+dye%0D%0Asensitizer+pada+DSSC.+Dari+hasil+sintesis+diperoleh+kristal+kompleks+Co(II)%0D%0AFenantrolin+berwarna+oranye+dengan+berat+0%2C552+gram+dan+rendemen+72%2C6%25.%0D%0AAnalisis+menggunakan+MSB+menunjukkan+momen+magnet+kompleks+Co(II)%0D%0AFenantrolin+sebesar+4%2C720+BM.+Data+spektrum+spektrofotometer+UV-Vis%0D%0Amenunjukkan+senyawa+kompleks+Co(II)+Fenantrolin+mengalami+pergeseran%0D%0Abatokromik+yang+ditandai+dengan+bergesernya+senyawa+pembentuknya+228+nm+ke%0D%0Apanjang+gelombang+267+nm+dengan+transisi+n%E2%86%92%CF%80*.+Data+Spektrum+FTIR+senyawa%0D%0Akompleks+Co(II)+Fenantrolin+menunjukkan+adanya+serapan+khas+senyawa+kompleks%0D%0A(M-N)+pada+bilangan+gelombang+420%2C48+cm-1%0D%0A%0D%0A.+Analisis+dekomposisi+termal%0D%0Amenunjukkan+terjadi+dekomposisi+massa+5+molekul+H2O+pada+rentang+suhu+50-%0D%0A100%C2%B0C+sebanyak+12%2C11%25%3B+pada+rentang+suhu+120-405%C2%B0C+terjadi+dekomposisi+massa%0D%0Aligan+fen+sebanyak+45%2C38%25.+Analisis+morfologi+menunjukkan+senyawa+kompleks%0D%0ACo(II)+Fenantrolin+memiliki+bentuk+tongkat+seperti+poros+dengan+tambahan+bentuk%0D%0Aprisma+(prism-like).+Hasil+pengujian+DSSC+diperoleh+nilai+efisiensi+sebesar+0%2C398%25%0D%0Adengan+tegangan+398%2C7+mV+dan+kuat+arus+sebesar+1%2C0+mA.%0D%0A%0D%0AKata+Kunci+%3AKobalt%2C+Fenantrolin%2C+1%2C10-+Fenantrolin%2C+sensitizer%2C+Dye+Sensitizer+Solar%0D%0ACell(DSSC)%0D%0A%0D%0AABSTRACT%0D%0A%0D%0ASYNTHESIS%2C+CHARACTERIZATION%2C+AND+APLICATION+OF%0D%0ACOBALT(II)+COMPLEX+WITH+1%2C10-+PHENANTROLINE+LIGAND+AS+A%0D%0ADYE+SENSITIZER+IN+DYE+SENSITIZED+SOLAR+CELL+(DSSC)%0D%0A%0D%0ABy%0D%0A%0D%0AAURA+DHAYANG+FIARIZKY%0D%0A%0D%0ASynthesis+of+complex+compound+with+metal+ion+Co(II)+and+ligand+1%2C10-%0D%0APhenanthroline+has+been+carried+out+with+a+concentration+ratio+of+1%3A3.+The%0D%0Asynthesized+Co(II)+phenanthroline+complex+compound+was+characterized+using%0D%0AMSB+to+determine+the+value+of+the+magnetic+moment%2C+UV-Vis+spectrophotometer%0D%0Ato+determine+the+wavelength+shift%2C+FTIR+spectrophotometer+to+determine+typical%0D%0Afunctional+groups%2C+DTA-TGA+analysis+to+determine+the+formula+and+decomposition%0D%0Aof+the+compound%2C+and+SEM+analysis+to+determine+the+crystal+morphology+of%0D%0Acomplex+compounds.+The+synthesized+Co(II)+Phenanthroline+complex+was+applied%0D%0Aas+a+dye+sensitizer+in+DSSC.+From+the+results+of+the+synthesis%2C+it+was+obtained+that%0D%0Athe+crystal+complex+of+Co(II)+Fenanthroline+was+orange+with+a+weight+of+0.552%0D%0Agrams+and+a+yield+of+72.6%25.+Analysis+using+MSB+showed+that+the+magnetic+moment%0D%0Aof+the+phenanthroline+Co(II)+complex+was+4.720+BM.+Spectrophotometer+UV-Vis%0D%0Aspectrophotometer+data+showed+that+the+complex+compound+Co(II)+phenanthroline%0D%0Aunderwent+a+bathochromic+shift+which+was+indicated+by+the+shift+of+its+constituent%0D%0Acompound+from+228+nm+to+a+wavelength+of+267+nm+with+a+transition+of+n%E2%86%92%CF%80*.+Data%0D%0Aon+the+FTIR+spectrum+of+the+phenanthroline+Co(II)+complex+compound+showed+a%0D%0A%0D%0Atypical+absorption+of+the+complex+compound+(MN)+at+a+wave+number+of+420.48+cm-%0D%0A1%0D%0A%0D%0A.+Thermal+decomposition+analysis+showed+that+there+was+a+mass+decomposition+of%0D%0A5+Hmolecules2Oin+the+temperature+range+of+50-100%C2%B0C+as+much+as+12.11%25%3B+in+the%0D%0Atemperature+range+of+120-405%C2%B0C+the+fen+ligand+mass+decomposition+was+45.38%25.%0D%0A%0D%0AMorphological+analysis+showed+that+the+Co(II)+phenanthroline+complex+had+a+rod-%0D%0Alike+shape+with+an+additionalshapeprism-like.+DSSC+test+results+obtained+an%0D%0A%0D%0Aefficiency+value+of+0.398%25+with+a+voltage+of+398.7+mV+and+a+current+of+1.0+mA.%0D%0A%0D%0AKey+Words+%3ACobalt%2C+Phenantroline%2C+1%2C10-+Phenantroline%2C+sensitizer%2C+Dye+Sensitizer%0D%0ASolar+Cell(DSSC)&rft.publisher=FAKULTAS+MATEMATIKA+DAN+IL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