title: STABILITAS DAN KEMAMPUAN MEMBRAN YANG MENGANDUNG  POLI-BADGE 3:1 UNTUK TRANSPOR FENOL MENGGUNAKAN  METODE POLYMER INCLUSION MEMBRANE (PIM)
creator: Sefi , Amelleony PutrI
subject: 502 Aneka ragam tentang ilmu pengetahuan alam
description: Pemisahan dan pemurnian fenol dari air limbah dapat dilakukan dengan  menggunakan teknologi membran cair berbasis Poli-BADGE 3:1 sebagai senyawa  pembawa. Membran cair yang mengandung senyawa pembawa tersebut dapat  digunakan, karena fenol dan senyawa pembawa memiliki sisi aktif yang sama.    Penelitian mengenai stabilitas dan kemampuan membran yang mengandung Poli-  BADGE 3:1 untuk transpor fenol telah dilakukan menggunakan metode Polymer    Inclusion Membrane (PIM). Penelitian ini bertujuan untuk mengetahui stabilitas  membran PIM dengan pengaruh variasi plasticizer, jenis dan konsentrasi garam,  serta kemampuan membran PIM melalui pemakaian berulang dan umur membran.  Membran PIM dipreparasi dengan melarutkan Poli-BADGE 3:1, polivinil klorida  (PVC), dan dibenzil eter (DBE). Penentuan konsentrasi fenol sesudah proses  transpor dianalisis dengan metode spektrofotometri UV-Vis dengan penambahan  4-aminoantipirin dan absorbansinya diukur pada panjang gelombang 456 nm.  Hasil penelitian menunjukkan bahwa stabilitas membran dicapai pada  penambahan plasticizer 0,3132 g dengan konsentrasi fenol tertransfor sebesar  60,84%. Penambahan jenis garam NaCl pada sumber menunjukkan hasil optimum  dibandingkan jenis garam lainnya, yakni mampu mentranspor fenol pada fasa  penerima sebesar 56,16%. Transpor fenol dengan melakukan penambahan NaCl  0,01 M di fasa sumber dan penerima menghasilkan fenol yang tertranspor  sebanyak 54,60% dan 45,79%. Pada uji kemampuan membran PIM melalui  pemakaian berulang dilakukan 5 kali pengulangan transpor. Pemakaian berulang  tanpa pencucian mampu mentranspor fenol sebesar 56,96%, 49,74%, 34,68%,  29,39%, dan 24,75%, serta pada pemakaian berulangan dengan pencucian mampu  mentranspor fenol sebesar 56,44%, 41,33%, 33,22%, 27,90%, dan 20,72%. Tanpa  penambahan garam, kemampuan transpor membran hanya 45 hari tetapi dengan  penambahan KNO3 0,1 M kemampuannya meningkat menjadi 61 hari.  Kata kunci: fenol, PIM, Poli-BADGE, stabilitas, kemampuan  Separation and purification of phenol from wastewater can be done using liquid  membrane technology based on Poly-BADGE 3:1 as a carrier compound. Liquid  membranes containing these carrier compounds can be used, because phenol and  carrier compounds have the same active side. Research on the stability and ability  of membranes containing Poly-BADGE 3:1 for phenol transport has been carried  out using the Polymer Inclusion Membrane (PIM) method. This study aims to  determine the stability of PIM membranes with the influence of plasticizer  concentration, type and concentration of salt, as well as the ability of PIM  membranes through repeated use and membrane life. PIM membrane was  prepared by dissolving 3:1 poly-BADGE, polyvinyl chloride (PVC), and dibenzyl  ether (DBE). Determination of phenol concentration after the transport process  was carried out by UV-Vis spectrophotometric method with the addition of 4-  aminoantipyrine and the absorbance was measured at a wavelength of 456 nm.  The results showed that membrane stability was achieved at the addition of 0.3132  g plasticizer with a transported phenol concentration of 60.84%. The addition of  NaCl salt type at the source showed optimum results compared to other types of  salt, which was able to transport phenol in the receiving phase by 56.16%. Phenol  transport by adding 0.01 M NaCl in the source and receiver phases resulted in  phenol transported as much as 54.60% and 45.79%. In the test of the ability of the  PIM membrane through repeated use, 5 repetitions of transport were carried out.  Repeated use without washing was able to transport phenol by 56.96%, 49.74%,  34.68%, 29.39%, and 24.75%, and in repeated use with washing was able to  transport phenol by 56.44%, 41.33%, 33.22%, 27.90%, and 20.72%. Without the  addition of salt, the membrane transport ability was only days but with the  addition of 0.1 M KNO3 the ability increased to 61 days.  Keywords: phenol, PIM, Poly-BADGE, stability, capability
publisher: FAKULTAS MATEMATIKA DAN ILMU PENGETAHUAN ALAM 
date: 2024-08-07
type: Skripsi
type: NonPeerReviewed
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identifier: http://digilib.unila.ac.id/81833/1/ABSTRAK%20-%20Sefi%20Amelleony%20Putri.pdf
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identifier: http://digilib.unila.ac.id/81833/2/SKRIPSI%20FULL%20-%20Sefi%20Amelleony%20Putri.pdf
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identifier: http://digilib.unila.ac.id/81833/3/SKRIPSI%20TANPA%20BAB%20PEMBAHASAN%20-%20Sefi%20Amelleony%20Putri.pdf
identifier:   Sefi , Amelleony PutrI  (2024) STABILITAS DAN KEMAMPUAN MEMBRAN YANG MENGANDUNG POLI-BADGE 3:1 UNTUK TRANSPOR FENOL MENGGUNAKAN METODE POLYMER INCLUSION MEMBRANE (PIM).  FAKULTAS MATEMATIKA DAN ILMU PENGETAHUAN ALAM , UNIVERSITAS LAMPUNG.     
relation: http://digilib.unila.ac.id/81833/